RAFT synthesis of temperature-responsive random copolymers of PEGMEMA and MAA

Authors

Eduardo T. Atayde ⋅ PH Natural Sciences Research Institute, University of the Philippines Diliman
Lizette M. Lao ⋅ PH Institute of Chemistry, University of the Philippines Diliman
Monica C. Berenguel ⋅ PH Natural Sciences Research Institute, University of the Philippines Diliman
Rachelle Anne Geline P. Ureta ⋅ PH Material Science and Engineering Program, University of the Philippines Diliman
Susan D. Arco ⋅ PH Natural Sciences Research Institute, University of the Philippines Diliman

Abstract

Temperature-responsive random copolymers of poly(ethylene glycol) methyl ether methacrylate (PEGMEMA) and methacrylic acid (MAA) were successfully synthesized using reversible addition-fragmentation chain transfer (RAFT) polymerization as indicated by 1H-NMR spectroscopy. The generated atomic force microscopy (AFM) images showed that the aggregations formed by the resulting polymers are spherical in shape. The lower critical solution temperature (LCST) was investigated through dynamic light scattering. It was found out that there is a correlation between the amount of MAA and the copolymers’ LCST showing its potential application in drug delivery systems.

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Issue

2015: Proceedings of the 33rd Samahang Pisika ng Pilipinas Physics Congress

Article ID

SPP-2015-3C-07

Section

Condensed Matter Physics and Materials Science

Published

2015-06-03

How to Cite

[1]

ET Atayde, LM Lao, MC Berenguel, RAGP Ureta, and SD Arco, RAFT synthesis of temperature-responsive random copolymers of PEGMEMA and MAA, Proceedings of the Samahang Pisika ng Pilipinas 33, SPP-2015-3C-07 (2015). URL: https://proceedings.spp-online.org/article/view/1102.