Comparative transport studies of '1212' superconductors
Abstract
The purpose of this study is to ascertain the nature of the 30-K shift in the critical temperature (Tc) in exchanging the Tl cation in TlBa2CaCu2O6+δ (Tl-1212, Tc ~ 90 K) with the Hg cation to produce HgBa2CaCu2O6+δ (Hg-1212, Tc ~ 120 K). This rare availability of high quality samples of both '1212' species makes this study possible, and could shed new light on the still-unexplained mechanism of high-temperature superconductivity. Since the Hg-1212 films were fabricated from Tl-1212 by replacing Tl cations by Hg cations the superconducting '1212' layered structured is preserved under this cation exchange; therefore the Tc shift is not due to the anisotropic layered structure prevalent in high-temperature superconductors, but more likely due to differences in the electronic structure and charge carrier density. It will be shown that the Tc shift is due primarily to a shift in charge carrier density.