Photoluminescence studies of silver-doped and magnesium-doped zinc oxide thin films on silicon prepared by intermittent spray pyrolysis

Authors

  • Jefferson M. Abrenica National Institute of Physics, University of the Philippines Diliman
  • Raymund C. Veloz National Institute of Physics, University of the Philippines Diliman
  • Mylenne Manrique National Institute of Physics, University of the Philippines Diliman
  • Heinritz Majella S. Miguel National Institute of Physics, University of the Philippines Diliman
  • Precy Mae C. Calaque National Institute of Physics, University of the Philippines Diliman
  • Ma. Herminia M. Balgos National Institute of Physics, University of the Philippines Diliman
  • Armando S. Somintac National Institute of Physics, University of the Philippines Diliman
  • Melvin John F. Empizo National Institute of Physics, University of the Philippines Diliman
  • Kohei Yamanoi Institute of Laser Engineering, Osaka University
  • Toshihiko Shimizu Institute of Laser Engineering, Osaka University
  • Nobuhiko Sarukura Institute of Laser Engineering, Osaka University

Abstract

Silver-doped (Ag) and magnesium-doped (Mg) zinc oxide (ZnO) thin films were fabricated on silicon using intermittent spray pyrolysis. Undoped ZnO thin film was also fabricated as a reference. The scanning electron microscope (SEM) images of the ZnO thin films revealed a very rough surface morphology. The x-ray diffraction (XRD) profile showed that the thin films have a hexagonal wurtzite crystal structure. The UV-VIS spectra showed that the ZnO thin films have high transparency in the visible region. Wide-scan photoluminescence (PL) spectra of all the ZnO thin films indicate UV and visible emissions at around 380-400 nm and 510-530 nm, respectively. An increase in green emission and decrease in bandgap for Ag-doped ZnO thin film were observed, making Ag a viable dopant to extend the operation of future ZnO-based optoelectronic devices to the visible region.

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Published

2014-10-17

How to Cite

[1]
“Photoluminescence studies of silver-doped and magnesium-doped zinc oxide thin films on silicon prepared by intermittent spray pyrolysis”, Proc. SPP, vol. 32, no. 1, p. SPP2014-PB-13, Oct. 2014, Accessed: Mar. 29, 2026. [Online]. Available: https://proceedings.spp-online.org/article/view/1885