Carbon-polydimethylsiloxane composites as paste electrodes: Electrochemical characterization and surface morphological analysis
Abstract
Carbon-polymer composite materials for carbon paste electrode (CPE) application were prepared using graphite and multi-walled carbon nanotubes (MWCNT) as conducting particles and polydimethylsiloxane (PDMS) as binder. Different viscosities of PDMS were used and its effect on the electrochemical response, surface area and specific capacitance of the electrodes were studied and correlated to surface morphology. Electrochemical performance was evaluated by studying the redox response of each CPE towards K4[Fe(CN)6], p-benzoquinone, and ascorbic acid employing Cyclic Voltammetry. In general, the MWCNT-based electrode showed good chemical reversibility, while electrochemical reversibility study showed hyperNernstian response for all electrodes.